Expat Health Insurance
Cigna Global Health Insurance.
Medical insurance specifically designed for expats. With Cigna, you won't have to rely on foreign public health care systems, which may not meet your needs. Cigna allows you to speak to a doctor on demand, for consultations or instant advice, wherever you are in the world. They also offer full cancer care across all levels of cover, and settle the cost of treatments directly with the provider.
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I'd also recommend contacting your respective embassy in Angola and asking for contact details for organisations that might be looking for volunteers.
Getting to and from the work you may want to do will be a challenge, most expats in Angola don't have their own car - and if the organisation you wish to volunteer for can't arrange transport - you may, unfortunately be stuck at home. That said, there's always room for unique problem-solving efforts in this African country, so just believe you'll find a way at some point.
Also, for more info about living in Angola, check out the Expat Arrivals PDF/Printable guide.